Update: the anime is called "Shining Hearts" and the character looks different in the show, dressed like a pirate. The version I thought looked like Celestina was a "professor variant" which was made as a figurine but has nothing to do with the show or game. Disappointing.
@Lorgar She looks like a loli based on her head-to-body ratio, but that may just be the art-style. Gives me Tim Burton vibes.